近些年来中国的经济发展迅速,镀锌钢板是国内消费增长速度较快的钢材品种之一。 In recent years, China's economy has developed rapidly, and galvanized steel plate is one of the steel varieties with a rapid growth rate in domestic consumption. 为改善镀锌层耐蚀性能,一般都要对镀锌层进行适当的钝化处理,来提高镀锌层在环境中的热力学稳定性。钝化处理属一种化学钝化膜技术,它是通过化学或电化学等手段,使金属或镀层表面由活泼态转变为钝化态的过程。实验结果表明:在镀层表面采用化学方法生成一层钝化膜,可以大大提高锌镀层的抗蚀性能。按照锌镀层出现红锈(即铁开始遭受腐蚀)的时间来评价,钝化膜的耐蚀性能相当于13μm锌镀层的耐蚀性。 In order to improve the corrosion resistance of galvanized coating, it is generally necessary to improve the thermodynamic stability of galvanized coating in the environment. Passivation treatment is a chemical passivation membrane technology, it is the metal or coating surface from active state to passivation state through chemical or electrochemical means process. The experimental results show that the coating surface can greatly improve the corrosion resistance of the zinc coating. According to the time when the zinc coating appears red rust (i. e. iron starts to suffer corrosion), the corrosion resistance of the passivation film is equivalent to the corrosion resistance of 13 μ m zinc coating. 钝化即是对镀锌板进行铬酸盐钝化处理可以形成钝化膜,溶液钝化族中的三价铬难溶于水,化学性质不活泼,起骨架作用,而其中的六价铬易溶于水,能在钝化膜划伤时起到再钝化的作用,具有钝化膜的治愈作用。因此,在一定限度内,钝化膜能防止蒸汽或潮湿空气直接侵蚀镀锌板,起保护作用。 Passivation is the chromate passivation treatment of galvanized plate can form a passivation film, the trivalent chromium in the solution passivation group is insoluble in water, the chemical properties are not active, play the skeleton role, and the hexavalent chromium is easily soluble in water, can play the role of passivation when the passivation film is scratched, has the healing effect of passivation film. Therefore, within a certain limit, passivation film can prevent steam or humid air directly erosion of galvanized plate, play a protective role. |